3-Methyl-N-phen­ylbenzamide

نویسندگان

  • B. Thimme Gowda
  • Sabine Foro
  • B. P. Sowmya
  • Hartmut Fuess
چکیده

The conformation of the C=O bond in the structure of the title compound, C(14)H(13)NO, is anti to the meta-methyl substituent in the benzoyl ring. The conformations of the N-H and C=O bonds in the amide group are also anti to each other. The asymmetric unit of the structure contains two mol-ecules. The bond parameters are similar to those in N-(phen-yl)benzamide, 2-methyl-N-(phenyl)-benz-amide and other benzanilides. The amide group -NHCO- forms dihedral angles of 20.97 (34) and 45.65 (19)° with the benzoyl rings, and 41.54 (25) and 31.87 (29)° with the aniline rings, in the two independent mol-ecules. The benzoyl and aniline rings adopt dihedral angles of 22.17 (18) and 75.86 (12)° in the two independent mol-ecules. In the crystal structure, mol-ecules are linked into chains by inter-molecular N-H⋯O hydrogen bonds.

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

[Methyl-14C]-choline incorporation into nude mice bearing tumor xenografts-correlation with [methyl-3H]-thymidine: A pilot study

Background: Many in vitro studies suggested that choline incorporation into many types of tumors is related to cell proliferation. Whether in vivo choline incorporation is related also to cell proliferation or not was my question. Therefore, the aim of this pilot study was to investigate the relationship of in vivo [methyl- 14C]-choline incorporation and in vivo [methyl-3H]- thymidine incorpora...

متن کامل

N-methyl pyridinium-p-toluene Sulfonate (NMPyTs) catalyzed synthesis of pyrano[2,3-c]pyrazoles

Abstarct:A simple one-pot synthesis of pyrano[ 2,3-c]pyrazoles was developed by a three-component reaction of various benzaldehydes, malononitrile and 1-phenyl or hydro-3-methyl-1H-pyrazol-5(4H)-one in the presence of N-methyl pyridinium p-toluene sulfonate (NMPyTs) as a catalyst. All of the synthesized compounds were identified by IR, 1H NMR, 13C NMR and mass spectroscopy techniques. In the me...

متن کامل

The Length Dependent Activity of Oximes on Reactivation of Tabun Inhibited Acetylcholinesterase; A Theoretical Study

In this work, the effect of ligand's length on interaction energy of six oximes, A [2-(hydroxyimino)-N-((1-(2-(2-((hydroxyimino)methyl)-1H-imidazol-1-yl)ethyl)-1H-1,2,3-triazol-4-yl)methyl)acetamide], B [2-(hydroxyimino)-N-((1-(3-(2-((hydroxyimino)methyl)-1H-imidazol-1-yl)propyl)-1H-1,2,3-triazol-4-yl)methyl)acetamide], C [2-(hydroxyimino)-N-((1-(4-(2-((hydroxyimino)methyl)-1H-imidazol-1-yl)but...

متن کامل

Synthesis of a carbon-14 analogue of N-(aryl-methyl)-3-phenyl-acryl amidine-[carboxy-14C] and its derivatives as NR2B-selective NMDA receptor antagonist

Four amidine NR2B-selective NMDA receptor antagonists, N-( 2-methoxy benzyl) -3-phenyl-acrylamidine, N-[diduterio(2-methoxyphenyl) methyl]-3-phenyl-acrylamidine, N-benzyl-3-phenyl-acryl amidine and N-[diduterio(phenyl)methyl]-3-phenyl-acrylamidine, all fourlabeled with carbon-14 in the 1-position, have been synthesized as part of 5-step sequence fromBa14CO3.

متن کامل

Photocatalyst Ag@N/TiO2 Nanoparticles: Fabrication, Characterization, and Investigation of the Effect of Coating on Methyl Orange Dye Degradation

In this research, N-doped TiO2 (N/TiO2) nanoparticles have been synthesized by a sol-gel method. N/TiO2 nanoparticle has been coated with Ag metal by photochemical method. Triethylamine, N(CH3CH2)3, have been used as precursors of Nitrogen, titanium tetraiso-propoxide (TTIP), Ti[OCH(CH3)2]4, used as precursors of titanium and Ag(NO3)2 used as precursors of Silver in synthesis of these nanoparti...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

ثبت نام

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

عنوان ژورنال:

دوره 64  شماره 

صفحات  -

تاریخ انتشار 2008